Low-chromium ferritic stainless steel 0Cr11Ti (AISI 409) and 00Cr11Ti (AISI 409L) are two commonly used stainless steel grades with low carbon content (0.08-0.13 wt%). Due to the low chromium content, these steels are prone to localized corrosion and oxidation, so it is important to know the oxidation resistance of these materials for their potential applications. It is known that low-chromium ferritic stainless steels are susceptible to chloride stress corrosion cracking and hydrogen embrittlement, and for this reason, their oxidation resistance is often considered as an important factor.
The oxidation resistance of 0Cr11Ti and 00Cr11Ti materials is usually studied through tests such as the cyclic oxidation test, the isothermal oxidation test, or the accelerated oxidation test, which involve the exposure of the material to an oxidizing environment at elevated temperatures. The oxidation rate is then evaluated by measuring the mass gain of the oxidation products by gravimetric analysis and/or calculating the thickness of the oxide layer. Results from these studies have shown that 0Cr11Ti and 00Cr11Ti stainless steels exhibit moderate oxidation resistance, with an oxidation rate of approximately 0.2 to 1.5 micron/year. These results are comparable with those of higher chromium ferritic grades such as AISI 441, which exhibits an oxidation rate of up to 4.0 micron/year.
The oxidation resistance of the 0Cr11Ti and 00Cr11Ti stainless steel can be further improved by forming oxide-rich layers on the surface of the material to provide a protective layer. In this process, a coat of compositions such as silica, alumina, tungsten, chromium and titanium are deposited on the surface. These layers provide an effective barrier against attack by oxygen, and can also act as a diffusion barrier to slow down the oxidation process.
In conclusion, the oxidation resistance of 0Cr11Ti and 00Cr11Ti stainless steel is moderate and can be improved by forming an oxidant resistant coating. Despite the low chromium content, these steels are suitable for certain applications where oxidation resistance is not a primary concern. Thermal cycling and thermal shock tests have demonstrated their mechanical and corrosion resistance, making them an attractive material for use in certain applications.