Pyrometallurgy is the use of high heat within a furnace or a series of furnaces to extract or refine base metals or precious metals from ores. The earliest uses of pyrometallurgy date back centuries, including the use of furnaces to smelt copper and iron ore. In the Middle Ages and early modern period, pyrometallurgy was used in the production of many base and precious metals.
Pyrometallurgy is based on the ability of the ore to be heated and fused, allowing the desired metal to then be separated and collected. In the process, an ore is heated to temperatures either below or above the melting point of the metal itself. This is done for a variety of reasons, including the removal of impurities and concentration of the ore.
Many different types of furnaces can be used in pyrometallurgy. They include electric arc furnaces (used to process iron ore), smelting furnaces, reverberatory furnaces (used to process copper and lead ores) and crucibles (used to produce high purity alloys). Ores containing sulphur or arsenic can be treated with fluxing agents to ensure a clean, pure product.
The process of pyrometallurgy is typically broken down into steps, including pre-treatment, smelting, and refining. Each step requires specific temperatures and techniques in order to achieve the desired results. Pre-treatment can involve the calcination of the ore, which is done by heating the ore to temperatures high enough to drive off the unwanted moisture and carbonates. This can be accomplished by either roasting or skipping. Smelting is the most energy-intense step and is done by heating the ore to melting point, mixing it with flux (an oxidation reducing agent) and removing the unwanted impurities (such as sulfur, metal oxides, phosphorus, etc.) to take advantage of the ores separating behavior. The last step, refining, is done by further heating the metal until it reaches the desired level of purity. As the metals are heated they will form certain gases which can be used to further purify the metal.
Pyrometallurgy has been used throughout centuries of industry to refine a variety of metals and alloys. It is still used today as an economical and more efficient way to produce a variety of products from mined ore. As methods of refining and processing materials continue to be developed, pyrometallurgy is likely to remain an important part of the metallurgical process.