Corrosion Fatigue
Corrosion fatigue is a type of mechanical failure caused by the combined action of fatigue and corrosion processes. The term fatigue refers to the weakening of materials subjected to cyclic or repeated stresses, while corrosion is a gradual degradation of materials caused by electrochemical or chemical reactions with the environment. Metal fatigue and corrosion can occur separately, or they can act together to generate corrosion fatigue. When these two types of behavior interact in a corrosive environment, the fatigue failure rate of a material increases, resulting in a much shorter lifetime of a material or a machine component.
The interaction of fatigue and corrosion can occur in a variety of ways. For example, corrosion can weaken the surface layers of a material, making them more prone to fatigue damage. It can also cause corrosion pits or other surface imperfections that can act as stress riser promoting fatigue failure at a much lower stress level than what is usually required. In addition, corrosion can create a build-up of surface films or deposits of corrosion products, which can effectively retard the fatigue process. As the cycle continues, the buildup of these films can result in a net decrease in the fatigue life of the material.
The cause of corrosion fatigue is often attributed to the electrochemical processes that occur at the interface between a material and its environment. These processes can cause the formation of unstable surface films of corrosion products, which will weaken the surface of the material, making it more susceptible to mechanical damage from fatigue. In addition, corrosion can cause pitting, which creates uneven surfaces and creates stresses in the material, lowering the cycle stresses required to cause damage.
Corrosion fatigue can be prevented or minimized with the use of protective coatings, such as chromium oxide, zinc oxide, and tin oxide. These coatings are designed to form a thin protective layer over the material surface and protect it against corrosive agents and cyclic stresses. Additionally, anodizing and electroplating can also be used to improve corrosion resistance.
Other methods used to reduce corrosion fatigue include ensuring that the material composition is suitable for its intended environment, as well as designing a geometry or shape that distributes the stress in the material more evenly. In addition, surface treatments and heat treatments can be used to improve the materials strength and fatigue resistance.
In conclusion, corrosion fatigue is a significant and damaging form of mechanical failure that can drastically reduce the life of material or components. However, proactive measures such as protective coatings and surface treatments, as well as careful material selection and design, can help to reduce and prevent the occurrence of corrosion fatigue.