Introduction
Manganese boride (MnB) is a hard and brittle refractory material composed of manganese and boron. Due to the low solubility of MnB in the melt, it is impossible to achieve homogeneous impregnation with conventional melting and solidification methods. Therefore, MnB can easily form large discontinuities or cracks during solidification. For this reason, proper techniques need to be employed during processing in order to ensure that the solidified MnB has good mechanical properties. In this paper, the microstructure of the MnB discontinuity and associated fractures are discussed.
MnB Structure
MnB is composed of manganese boride which crystallizes in a hexagonal lattice. The composition of the material can be expressed as MnB_x where x is typically between 0.56 and 0.66. MnB usually forms in the form of elongated needle-like crystals with their long axes perpendicular to their surface orientation. The needles have an average diameter of 0.1-3 μm and a length of 0.5-20 μm. This needle-like morphology is typical of the needle-like microstructures resulting from the decomposition of liquid iron-rich melts. Due to the extreme hardness of the crystals, the MnB material exhibits outstanding wear resistance, corrosion resistance, and thermal stability.
MnB Discontinuities
Discontinuities are caused by the inability of melted MnB to fill the entire mold due to segregation or inhomogeneous solidification. This type of discontinuity can result in undesirable mechanical properties, such as low toughness and low ductility. The formation of large discontinuities could be caused by several factors. The most common factors are the use of inadequate pouring temperatures, improper pouring techniques, and lack of surface finishing.
MnB Fractures
Due to their extremely hard and brittle nature, MnB materials exhibit low fracture toughness. Small cracks due to incoming stress or thermal shocks can cause serious damage in the MnB matrix. Fractures in MnB materials can be divided into two main categories: transgranular and intergranular fractures. The transgranular fractures occur in the MnB grains, while intergranular fractures occur at the grain boundaries.
Conclusion
Manganese boride is a hard and brittle refractory material which forms needle-like crystals. Discontinuities due to segregation or inhomogeneous solidification lead to reduced fracture properties and can cause low fracture toughness. Transgranular and intergranular fractures may result from incoming stress and thermal shocks. Appropriate processing techniques should be employed in order to ensure that the MnB exhibits good mechanical properties.